Isotopic imaging using fsLA single-collector ICP-SFMS for direct U/Th dating of small archaeological carbonates - INSU - Institut national des sciences de l'Univers
Article Dans Une Revue Analytical Chemistry Année : 2022

Isotopic imaging using fsLA single-collector ICP-SFMS for direct U/Th dating of small archaeological carbonates

Résumé

We present a new methodology for the U/Th dating of carbonate materials using femtosecond laser ablation single-collector inductively coupled plasma sector field mass spectrometry (fsLA single-collector ICP-SFMS), isotopic mappings, and image processing. This approach allows working on samples at very low U levels (ng·g$^{–1}$). One of the major advantages of this imaging method is that it allows us to exploit deteriorated samples that could not be analyzed by conventional bulk U/Th dating methods, thanks to the identification of contaminated or leached areas at the scale of a few tens of microns and the subsequent correction for detrital 230Th incorporation. Only a few milligrams of material are required for measurement, which allows us to work on small samples such as shell fragments. The parameters of the fsLA single-collector ICP-SFMS coupling have been carefully optimized to ensure very high sensitivity detection and ultralow background while preserving good plasma robustness and a spatial resolution of 30 × 50 μm$^2$. The accuracy was evaluated from low-level U speleothems previously dated by a conventional U/Th dating technique involving digestion, resin purification, double spike, and detection by multicollector inductively coupled plasma mass spectrometry (MC-ICPMS). U/Th ages of two archaeological samples with U at low ng·g$^{–1}$ levels, a giant terrestrial snail shell and a burned ostrich eggshell, were determined. The measured U/Th ages are consistent with the expected ages determined by luminescence dating methods.
Fichier principal
Vignette du fichier
272088.pdf (654.44 Ko) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03550046 , version 1 (28-02-2023)

Identifiants

Citer

Loïc Martin, Asmodée Galy, Gaëlle Barbotin, Fanny Claverie, Edwige Pons-Branchu, et al.. Isotopic imaging using fsLA single-collector ICP-SFMS for direct U/Th dating of small archaeological carbonates. Analytical Chemistry, 2022, 94 (7), pp.3046-3055. ⟨10.1021/acs.analchem.1c02241⟩. ⟨hal-03550046⟩
131 Consultations
94 Téléchargements

Altmetric

Partager

More