<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of insu-03520060</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-17T14:45:16+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Influence of Water on the H2SO4 Yield from the Ozonolysis of 2,3-dimethyl-butene (TME) in Presence of SO2</title>
            <author role="crp">
              <persName>
                <forename type="first">Alexandre</forename>
                <surname>Kukui</surname>
              </persName>
              <email type="md5">6fe35cf914b3e459991ca52de1377cab</email>
              <email type="domain">cnrs-orleans.fr</email>
              <idno type="idhal" notation="string">alexandre-kukui</idno>
              <idno type="idhal" notation="numeric">735491</idno>
              <idno type="halauthorid" notation="string">30292-735491</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-3657-0414</idno>
              <idno type="IDREF">https://www.idref.fr/253133785</idno>
              <affiliation ref="#struct-185533"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Hui</forename>
                <surname>Chen</surname>
              </persName>
              <idno type="idhal" notation="numeric">768630</idno>
              <idno type="halauthorid" notation="string">714849-768630</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-0440-8156</idno>
              <affiliation ref="#struct-474628"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Véronique</forename>
                <surname>Daële</surname>
              </persName>
              <email type="md5">b94b29e0027360f3535bdb27ab016863</email>
              <email type="domain">cnrs-orleans.fr</email>
              <idno type="idhal" notation="string">veronique-daele</idno>
              <idno type="idhal" notation="numeric">175159</idno>
              <idno type="halauthorid" notation="string">14541-175159</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-2509-4077</idno>
              <idno type="IDREF">https://www.idref.fr/183874854</idno>
              <affiliation ref="#struct-474628"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Wahid</forename>
                <surname>Mellouki</surname>
              </persName>
              <email type="md5">7bf84baf3d1047633a5b9a16a8c4581c</email>
              <email type="domain">cnrs-orleans.fr</email>
              <idno type="idhal" notation="string">abdelwahid-mellouki</idno>
              <idno type="idhal" notation="numeric">181905</idno>
              <idno type="halauthorid" notation="string">30227-181905</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/H-5219-2011</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-6594-5262</idno>
              <idno type="IDREF">https://www.idref.fr/069655197</idno>
              <affiliation ref="#struct-474628"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Alexandre</forename>
                <surname>KUKUI</surname>
              </persName>
              <email type="md5">6fe35cf914b3e459991ca52de1377cab</email>
              <email type="domain">cnrs-orleans.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2022-01-10 18:36:03</date>
              <date type="whenModified">2025-06-04 03:26:03</date>
              <date type="whenReleased">2022-01-10 18:36:03</date>
              <date type="whenProduced">2016-12-14</date>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="11550">
                <persName>
                  <forename>Alexandre</forename>
                  <surname>KUKUI</surname>
                </persName>
                <email type="md5">6fe35cf914b3e459991ca52de1377cab</email>
                <email type="domain">cnrs-orleans.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">insu-03520060</idno>
            <idno type="halUri">https://insu.hal.science/insu-03520060</idno>
            <idno type="halBibtex">kukui:insu-03520060</idno>
            <idno type="halRefHtml">&lt;i&gt;American Geophysical Union, Fall Meeting 2016, abstract #A33E-0267&lt;/i&gt;, Dec 2016, San Francisco, United States</idno>
            <idno type="halRef">American Geophysical Union, Fall Meeting 2016, abstract #A33E-0267, Dec 2016, San Francisco, United States</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="INSU">INSU - Institut National des Sciences de l'Univers</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-ORLEANS">Université d'Orléans</idno>
            <idno type="stamp" n="CNES">CNES - Centre national d'études spatiales</idno>
            <idno type="stamp" n="OSUC" corresp="INSU">Observatoire des Sciences de l'Univers en région Centre</idno>
            <idno type="stamp" n="GIP-BE">GIP Bretagne Environnement</idno>
            <idno type="stamp" n="LPC2E" corresp="OSUC">Laboratoire de Physique et Chimie de l'Environnement et de l'Espace</idno>
            <idno type="stamp" n="CNRS_ICARE" corresp="UNIV-ORLEANS">Institut de Combustion Aérothermique Réactivité et Environnement</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="invited" n="0">No</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
            <note type="proceedings" n="0">No</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Influence of Water on the H2SO4 Yield from the Ozonolysis of 2,3-dimethyl-butene (TME) in Presence of SO2</title>
                <author role="crp">
                  <persName>
                    <forename type="first">Alexandre</forename>
                    <surname>Kukui</surname>
                  </persName>
                  <email type="md5">6fe35cf914b3e459991ca52de1377cab</email>
                  <email type="domain">cnrs-orleans.fr</email>
                  <idno type="idhal" notation="string">alexandre-kukui</idno>
                  <idno type="idhal" notation="numeric">735491</idno>
                  <idno type="halauthorid" notation="string">30292-735491</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-3657-0414</idno>
                  <idno type="IDREF">https://www.idref.fr/253133785</idno>
                  <affiliation ref="#struct-185533"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Hui</forename>
                    <surname>Chen</surname>
                  </persName>
                  <idno type="idhal" notation="numeric">768630</idno>
                  <idno type="halauthorid" notation="string">714849-768630</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-0440-8156</idno>
                  <affiliation ref="#struct-474628"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Véronique</forename>
                    <surname>Daële</surname>
                  </persName>
                  <email type="md5">b94b29e0027360f3535bdb27ab016863</email>
                  <email type="domain">cnrs-orleans.fr</email>
                  <idno type="idhal" notation="string">veronique-daele</idno>
                  <idno type="idhal" notation="numeric">175159</idno>
                  <idno type="halauthorid" notation="string">14541-175159</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-2509-4077</idno>
                  <idno type="IDREF">https://www.idref.fr/183874854</idno>
                  <affiliation ref="#struct-474628"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Wahid</forename>
                    <surname>Mellouki</surname>
                  </persName>
                  <email type="md5">7bf84baf3d1047633a5b9a16a8c4581c</email>
                  <email type="domain">cnrs-orleans.fr</email>
                  <idno type="idhal" notation="string">abdelwahid-mellouki</idno>
                  <idno type="idhal" notation="numeric">181905</idno>
                  <idno type="halauthorid" notation="string">30227-181905</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/H-5219-2011</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-6594-5262</idno>
                  <idno type="IDREF">https://www.idref.fr/069655197</idno>
                  <affiliation ref="#struct-474628"/>
                </author>
              </analytic>
              <monogr>
                <meeting>
                  <title>American Geophysical Union, Fall Meeting 2016, abstract #A33E-0267</title>
                  <date type="start">2016-12-14</date>
                  <settlement>San Francisco</settlement>
                  <country key="US">United States</country>
                </meeting>
                <imprint/>
              </monogr>
              <idno type="bibcode">2016AGUFM.A33E0267V</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">ATMOSPHERIC COMPOSITION AND STRUCTURE</term>
                <term xml:lang="en">ATMOSPHERIC COMPOSITION AND STRUCTUREDE: 0394 Instruments and techniques</term>
                <term xml:lang="en">ATMOSPHERIC COMPOSITION AND STRUCTUREDE: 0365 Troposphere: composition and chemistry</term>
                <term xml:lang="en">ATMOSPHERIC COMPOSITION AND STRUCTUREDE: 0340 Middle atmosphere: composition and chemistry</term>
                <term xml:lang="en">0317 Chemical kinetic and photochemical properties</term>
              </keywords>
              <classCode scheme="halDomain" n="sdu.ocean">Sciences of the Universe [physics]/Ocean, Atmosphere</classCode>
              <classCode scheme="halTypology" n="POSTER">Poster communications</classCode>
              <classCode scheme="halOldTypology" n="POSTER">Poster communications</classCode>
              <classCode scheme="halTreeTypology" n="POSTER">Poster communications</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>The influence of the water vapor content on the yield of H2SO4 from the ozonolysis of 2,3-dimethyl-butene (TME) in presence of SO2 was studied using laminar flow reactor coupled with Chemical Ionisation Mass Spectrometer (CIMS) for the H2SO4 monitoring within the range of H2O from 10 ppmv to 3×104 ppmv at different concentrations of TME, O3, SO2. The observed dependences of the H2SO4 yield on H2O concentration can be interpreted by assuming two different paths of the H2SO4 formation: 1) via the formation of SO3 in the reaction of Stabilized Criegee Intermediate (SCI) with SO2 (2a) followed by the reaction of SO3 with H2O (3) and 2) via the formation of stabilized secondary ozonide (SOZ) (2b) producing H2SO4 in the reaction with H2O (4a) in competition with the SOZ decomposition to other products (5): O3+TME =&gt; (CH3)2COO (1) (CH3)2COO + SO2 =&gt; SO3 (2a) =&gt; SOZ (2b) SO3 + H2O =&gt; H2SO4 (3) SOZ + H2O =&gt; H2SO4 (or SO3) (4a) SOZ + M =&gt; products (5) The yield of the SCI, SOZ and the rates of the SCI and SOZ decomposition relative to their reactions with SO2 and H2O, respectively, were estimated from the dependencies of the H2SO4 yield on the concentrations of the reactants.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-185533" status="VALID">
          <idno type="IdRef">167915916</idno>
          <idno type="ISNI">0000000406235273</idno>
          <idno type="RNSR">201220223J</idno>
          <idno type="ROR">https://ror.org/049k66y27</idno>
          <idno type="Wikidata">Q15967014</idno>
          <orgName>Laboratoire de Physique et Chimie de l'Environnement et de l'Espace</orgName>
          <orgName type="acronym">LPC2E</orgName>
          <date type="start">2012-01-01</date>
          <desc>
            <address>
              <addrLine>3A, Avenue de la Recherche Scientifique 45071 Orléans cedex 2</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.lpc2e.cnrs.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UMR7328" active="#struct-300045" type="direct"/>
            <relation active="#struct-300297" type="direct"/>
            <relation name="UMR7328" active="#struct-441569" type="direct"/>
            <relation name="UMR7328" active="#struct-458369" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-474628" status="VALID">
          <idno type="IdRef">130578657</idno>
          <idno type="ISNI">0000000092583805</idno>
          <idno type="RNSR">200817616T</idno>
          <idno type="ROR">https://ror.org/03txr3336</idno>
          <idno type="Wikidata">Q30261464</idno>
          <orgName>Institut de Combustion, Aérothermique, Réactivité et Environnement</orgName>
          <orgName type="acronym">ICARE</orgName>
          <date type="start">2007-01-01</date>
          <desc>
            <address>
              <addrLine>1C, avenue de la Recherche Scientifique, CS 50060, 45071 - Orléans Cedex 2</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://icare.cnrs.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UPR 3021" active="#struct-300297" type="direct"/>
            <relation name="UPR3021" active="#struct-441569" type="direct"/>
            <relation name="UPR3021" active="#struct-474627" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-300045" status="VALID">
          <idno type="IdRef">029349265</idno>
          <idno type="ISNI">0000 0001 2154 1736</idno>
          <idno type="ROR">https://ror.org/04kdfz702</idno>
          <idno type="Wikidata">Q3152437</idno>
          <orgName>Institut national des sciences de l'Univers</orgName>
          <orgName type="acronym">INSU - CNRS</orgName>
          <date type="start">2007-04-19</date>
          <desc>
            <address>
              <addrLine>INSU-CNRS3 rue Michel-Ange, 75794 Paris Cedex 16</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.insu.cnrs.fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300297" status="VALID">
          <idno type="IdRef">026402971</idno>
          <idno type="ISNI">0000 0001 2158 1666</idno>
          <idno type="ROR">https://ror.org/014zrew76</idno>
          <orgName>Université d'Orléans</orgName>
          <orgName type="acronym">UO</orgName>
          <desc>
            <address>
              <addrLine>Château de la Source - Avenue du Parc Floral - BP 6749 - 45067 Orléans cedex 2</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-orleans.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-458369" status="VALID">
          <idno type="ROR">https://ror.org/04h1h0y33</idno>
          <orgName>Centre National d’Études Spatiales [Paris]</orgName>
          <orgName type="acronym">CNES</orgName>
          <desc>
            <address>
              <addrLine>Siège social : 2 place Maurice Quentin, 75039 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://cnes.fr/fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-474627" status="VALID">
          <idno type="IdRef">232435111</idno>
          <idno type="ISNI">0000000405066498</idno>
          <idno type="ROR">https://ror.org/00s19x989</idno>
          <orgName>Institut des Sciences de l'Ingénierie et des Systèmes - CNRS Ingénierie</orgName>
          <orgName type="acronym">INSIS - CNRS</orgName>
          <date type="start">2009-11-01</date>
          <desc>
            <address>
              <addrLine>3 rue Michel-Ange, 75794, Paris cedex 16, France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.insis.cnrs.fr/fr</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>