Context. Gaia DR3 has offered the scientific community a remarkable dataset of approximately one million spectra acquired with the radial velocity spectrometer (RVS) in the calcium II triplet region, which is well suited to identify very metal-poor (VMP) stars. However, over 40% of these spectra have no released parameters by Gaia's GSP-Spec pipeline in the domain of VMP stars, whereas VMP stars are key tracers of early Galactic evolution.
Aims: We aim to provide spectroscopic metallicities for VMP stars using Gaia RVS spectra, thereby producing a catalogue of bright VMP stars distributed over the full sky that can serve as the basis for studies of early chemical evolution throughout the Galaxy.
Methods: We selected VMP stars using photometric metallicities from the literature and analysed the Gaia RVS spectra to infer spectroscopic metallicities for these stars.
Results: The inferred metallicities agree very well with literature high-resolution metallicities, with a median systematic offset of 0.1 dex and standard deviation of ∼0.15 dex. The purity of this sample in the VMP regime is ∼80%, with outliers representing a mere ∼3%.
Conclusions: We have built an all-sky catalogue of ∼1500 stars available, featuring reliable spectroscopic metallicities down to [Fe/H] ∼ −4.0, of which ∼1000 are VMP stars. More than 75% of these stars have either no spectroscopic metallicity value in the literature to date or have been flagged as unreliable in their literature spectroscopic metallicity estimates. This catalogue of bright (G < 13) VMP stars is three times larger than the current sample of well-studied VMP stars in the literature in this magnitude range, making it ideal for high-resolution spectroscopic follow-ups and studies of the properties of VMP stars in different parts of our Galaxy.

Full Table 1 is available at the CDS via anonymous ftp to https://cdsarc.cds.unistra.fr (ftp://130.79.128.5) or via https://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/683/L11