<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of insu-04815568v2</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-16T00:34:35+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Fluid-rock reaction path modeling of uranium mobility in granite-related mineralization: A case study from the Variscan South Armorican Domain</title>
            <author role="crp">
              <persName>
                <forename type="first">Khaled</forename>
                <surname>Bock</surname>
              </persName>
              <email type="md5">6bade6084201ba744cf32ae22dd0ef49</email>
              <email type="domain">univ-rennes.fr</email>
              <idno type="idhal" notation="numeric">1398180</idno>
              <idno type="halauthorid" notation="string">2578331-1398180</idno>
              <idno type="ORCID">https://orcid.org/0009-0000-9645-4637</idno>
              <affiliation ref="#struct-179899"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Yannick</forename>
                <surname>Branquet</surname>
              </persName>
              <idno type="halauthorid">55811-0</idno>
              <affiliation ref="#struct-179899"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Olivier</forename>
                <surname>Pourret</surname>
              </persName>
              <email type="md5">e40340c2522368c4b958cb656fed383a</email>
              <email type="domain">unilasalle.fr</email>
              <idno type="idhal" notation="string">olivier-pourret</idno>
              <idno type="idhal" notation="numeric">177086</idno>
              <idno type="halauthorid" notation="string">45908-177086</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/B-4399-2008</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-6181-6079</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.com/citations?user=MQ1uyJwAAAAJ&amp;hl=fr</idno>
              <idno type="IDREF">https://www.idref.fr/110139089</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/B-4399-2008</idno>
              <affiliation ref="#struct-570581"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Philippe</forename>
                <surname>Boulvais</surname>
              </persName>
              <idno type="halauthorid">179222-0</idno>
              <affiliation ref="#struct-179899"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Isabelle</forename>
                <surname>Dubigeon</surname>
              </persName>
              <email type="md5">20cf1a093e59ffbcfabe4b58e2a4c026</email>
              <email type="domain">univ-rennes.fr</email>
            </editor>
            <funder>NEEDS consortium (URAMOD project)</funder>
          </titleStmt>
          <editionStmt>
            <edition n="v1">
              <date type="whenSubmitted">2024-12-03 08:18:24</date>
            </edition>
            <edition n="v2" type="current">
              <date type="whenSubmitted">2024-12-11 11:39:56</date>
              <date type="whenModified">2026-02-07 05:29:42</date>
              <date type="whenReleased">2024-12-11 11:39:57</date>
              <date type="whenProduced">2025</date>
              <date type="whenEndEmbargoed">2024-12-11</date>
              <ref type="file" target="https://insu.hal.science/insu-04815568v2/document">
                <date notBefore="2024-12-11"/>
              </ref>
              <ref type="file" subtype="publisherPaid" n="1" target="https://insu.hal.science/insu-04815568v2/file/bock-2025.pdf" id="file-4830817-4206758">
                <date notBefore="2024-12-11"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="110795">
                <persName>
                  <forename>Isabelle</forename>
                  <surname>Dubigeon</surname>
                </persName>
                <email type="md5">20cf1a093e59ffbcfabe4b58e2a4c026</email>
                <email type="domain">univ-rennes.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">insu-04815568</idno>
            <idno type="halUri">https://insu.hal.science/insu-04815568</idno>
            <idno type="halBibtex">bock:insu-04815568</idno>
            <idno type="halRefHtml">&lt;i&gt;Applied Geochemistry&lt;/i&gt;, 2025, 178, pp.106241. &lt;a target="_blank" href="https://dx.doi.org/10.1016/j.apgeochem.2024.106241"&gt;&amp;#x27E8;10.1016/j.apgeochem.2024.106241&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Applied Geochemistry, 2025, 178, pp.106241. &amp;#x27E8;10.1016/j.apgeochem.2024.106241&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://creativecommons.org/licenses/by/4.0/">CC BY 4.0 - Attribution<ref corresp="#file-4830817-4206758"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="INSU">INSU - Institut National des Sciences de l'Univers</idno>
            <idno type="stamp" n="UNIV-RENNES1">Université de Rennes 1</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="GR" corresp="INSU">Géosciences Rennes</idno>
            <idno type="stamp" n="OSUR">Observatoire des Sciences de l'Univers de Rennes</idno>
            <idno type="stamp" n="GIP-BE">GIP Bretagne Environnement</idno>
            <idno type="stamp" n="COMUE-NORMANDIE">Normandie Université</idno>
            <idno type="stamp" n="UR1-HAL">Publications labos UR1 dans HAL-Rennes 1</idno>
            <idno type="stamp" n="UR1-SDLM">UR1 - publications SDLM</idno>
            <idno type="stamp" n="TEST-UR-CSS">TEST Université de Rennes CSS</idno>
            <idno type="stamp" n="UNIV-RENNES">Université de Rennes</idno>
            <idno type="stamp" n="UNILASALLE">UniLaSalle</idno>
            <idno type="stamp" n="UR1-ENV">Pôle UnivRennes - Environnement</idno>
            <idno type="stamp" n="GR-FRODO" corresp="GR">Frodo</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Fluid-rock reaction path modeling of uranium mobility in granite-related mineralization: A case study from the Variscan South Armorican Domain</title>
                <author role="crp">
                  <persName>
                    <forename type="first">Khaled</forename>
                    <surname>Bock</surname>
                  </persName>
                  <email type="md5">6bade6084201ba744cf32ae22dd0ef49</email>
                  <email type="domain">univ-rennes.fr</email>
                  <idno type="idhal" notation="numeric">1398180</idno>
                  <idno type="halauthorid" notation="string">2578331-1398180</idno>
                  <idno type="ORCID">https://orcid.org/0009-0000-9645-4637</idno>
                  <affiliation ref="#struct-179899"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Yannick</forename>
                    <surname>Branquet</surname>
                  </persName>
                  <idno type="halauthorid">55811-0</idno>
                  <affiliation ref="#struct-179899"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Olivier</forename>
                    <surname>Pourret</surname>
                  </persName>
                  <email type="md5">e40340c2522368c4b958cb656fed383a</email>
                  <email type="domain">unilasalle.fr</email>
                  <idno type="idhal" notation="string">olivier-pourret</idno>
                  <idno type="idhal" notation="numeric">177086</idno>
                  <idno type="halauthorid" notation="string">45908-177086</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/B-4399-2008</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-6181-6079</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.com/citations?user=MQ1uyJwAAAAJ&amp;hl=fr</idno>
                  <idno type="IDREF">https://www.idref.fr/110139089</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/B-4399-2008</idno>
                  <affiliation ref="#struct-570581"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Philippe</forename>
                    <surname>Boulvais</surname>
                  </persName>
                  <idno type="halauthorid">179222-0</idno>
                  <affiliation ref="#struct-179899"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">10620</idno>
                <idno type="issn">0883-2927</idno>
                <title level="j">Applied Geochemistry</title>
                <imprint>
                  <publisher>Elsevier</publisher>
                  <biblScope unit="volume">178</biblScope>
                  <biblScope unit="pp">106241</biblScope>
                  <date type="datePub">2025</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1016/j.apgeochem.2024.106241</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">Uranium Mobilization</term>
                <term xml:lang="en">Fluid/Rock Interaction</term>
                <term xml:lang="en">Redox Potential</term>
                <term xml:lang="en">Thermo-Hydro-Chemical Modeling (TH-C)</term>
                <term xml:lang="en">Syn-kinematic Granite</term>
                <term xml:lang="en">Detachment Zones</term>
              </keywords>
              <classCode scheme="halDomain" n="sdu.stu.pe">Sciences of the Universe [physics]/Earth Sciences/Petrography</classCode>
              <classCode scheme="halDomain" n="sdu.stu.mi">Sciences of the Universe [physics]/Earth Sciences/Mineralogy</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>The mobilization of uranium in granite-related systems presents a complex interplay of chemical and hydrodynamic factors. This is particularly obvious within syn-orogenic detachment zones where per descensum surface-derived fluids interact with per ascensum deeply sourced hydrothermal fluids. In this study, we employ a thermo-hydro-chemical (TH-C) modeling approach to explore the multifaceted processes that govern uranium transport and deposition in such environments. Our findings indicate that uranium mobility is not solely determined by the oxidizing nature of the percolating surface-derived fluids. Actually, the oxidation-reduction potential of these fluids varies as they flow in the crust, ultimately adjusting towards more neutral or mildly reducing conditions conducive to uranium dissolution and precipitation. Even in the presence of magnetite, which enhances the reductive potential of the fluids, uranium continues to dissolve, albeit in much smaller quantities, with U(IV) being the predominant species in the aqueous phase. The study highlights the crucial roles of temperature, pH, and fluid/rock interaction ratios in influencing uranium leaching efficacy.&lt;p&gt;High fluid/rock ratios enhance uranium extraction from source rocks. A fluid/rock ratio around 1 is optimal, maximizing the dissolution of uranium-bearing minerals in the source rock and promoting the precipitation of uranium minerals in different locations along the fluid pathway due to changes in fluid chemistry. The TH-C modeling has the potential to be applied to a variety of other uranium deposits, developed below 300°C.&lt;/p&gt;</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-179899" status="VALID">
          <idno type="IdRef">027951189</idno>
          <idno type="RNSR">200012191F</idno>
          <idno type="ROR">https://ror.org/00vn0zc62</idno>
          <orgName>Géosciences Rennes</orgName>
          <orgName type="acronym">GR</orgName>
          <date type="start">2000-01-01</date>
          <desc>
            <address>
              <addrLine>Bâtiment 15 - Université de Rennes 1 - Campus de Beaulieu -263 Av du général Leclerc- CS 74205 - 35042 Rennes Cedex - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.geosciences.univ-rennes1.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-105160" type="direct"/>
            <relation active="#struct-300045" type="direct"/>
            <relation name="UMR6118" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-570581" status="VALID">
          <idno type="IdRef">198236433</idno>
          <idno type="RNSR">201622796N</idno>
          <orgName>Agro-écologie, Hydrogéochimie, Milieux et Ressources</orgName>
          <orgName type="acronym">AGHYLE</orgName>
          <date type="start">2016-01-01</date>
          <desc>
            <address>
              <addrLine>19, rue Pierre WAGUET – BP 30313 – 60026 Beauvais Cedexet3, rue du Tronquet - CS40118 - 76130 Mont-Saint-Aignan</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.unilasalle.fr/recherche/recherche-service-de-nos-ambitions/aghyle-2/</ref>
          </desc>
          <listRelation>
            <relation name="UP 2018.C101" active="#struct-527123" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-105160" status="VALID">
          <idno type="IdRef">26693823X</idno>
          <idno type="ROR">https://ror.org/015m7wh34</idno>
          <orgName>Université de Rennes</orgName>
          <orgName type="acronym">UR</orgName>
          <desc>
            <address>
              <addrLine>Campus de Beaulieu, 263 avenue Général Leclerc, CS 74205, 35042 RENNES CEDEX</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-rennes.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300045" status="VALID">
          <idno type="IdRef">029349265</idno>
          <idno type="ISNI">0000 0001 2154 1736</idno>
          <idno type="ROR">https://ror.org/04kdfz702</idno>
          <idno type="Wikidata">Q3152437</idno>
          <orgName>Institut national des sciences de l'Univers</orgName>
          <orgName type="acronym">INSU - CNRS</orgName>
          <date type="start">2007-04-19</date>
          <desc>
            <address>
              <addrLine>INSU-CNRS3 rue Michel-Ange, 75794 Paris Cedex 16</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.insu.cnrs.fr</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-527123" status="VALID">
          <idno type="IdRef">198281633</idno>
          <idno type="ROR">https://ror.org/05wy89733</idno>
          <orgName>UniLaSalle</orgName>
          <date type="start">2016-01-01</date>
          <desc>
            <address>
              <addrLine>19 rue Pierre Waguet – BP 30313 – 60026 BEAUVAIS cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.unilasalle.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>