Haze Formation in Warm H<SUB>2</SUB>-rich Exoplanet Atmospheres - INSU - Institut national des sciences de l'Univers Access content directly
Journal Articles The Planetary Science Journal Year : 2020

Haze Formation in Warm H2-rich Exoplanet Atmospheres

Chao He
  • Function : Author
Sarah M. Hörst
  • Function : Author
Nikole K. Lewis
  • Function : Author
Xinting Yu
  • Function : Author
Julianne I. Moses
  • Function : Author
Patricia Mcguiggan
  • Function : Author
Mark S. Marley
  • Function : Author
Eliza M. -R. Kempton
  • Function : Author
Caroline V. Morley
  • Function : Author
Jeff A. Valenti
  • Function : Author


New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of spectral features. We use laboratory simulations to explore photochemical haze formation in H2-rich exoplanet atmospheres at 800 K with metallicity either 100 or 1000 times solar. We find that haze particles are produced in both simulated atmospheres with small particle size (20-140 nm) and relatively low production rate (2.4 × 10-5 to 9.7 × 10-5 mg cm-3 hr-1), but the particle size and production rate is dependent on the initial gas mixtures and the energy sources used in the simulation experiments. The gas phase mass spectra show that complex chemical processes happen in these atmospheres and generate new gas products that can further react to form larger molecules and solid haze particles. Two H2-rich atmospheres with similar C/O ratios (∼0.5) yield different haze particle size, haze production rate, and gas products, suggesting that both the elemental abundances and their bonding environments in an atmosphere can significantly affect the photochemistry. There is no methane (CH4) in our initial gas mixtures, although CH4 is often believed to be required to generate organic hazes. However, haze production rates from our experiments with different initial gas mixtures indicate that CH4 is neither required to generate organic hazes nor necessary to promote the organic haze formation. The variety and relative yield of the gas products indicate that CO and N2 enrich chemical reactions in H2-rich atmospheres.
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Dates and versions

insu-03705180 , version 1 (27-06-2022)





Chao He, Sarah M. Hörst, Nikole K. Lewis, Xinting Yu, Julianne I. Moses, et al.. Haze Formation in Warm H2-rich Exoplanet Atmospheres. The Planetary Science Journal, 2020, 1, ⟨10.3847/PSJ/abb1a4⟩. ⟨insu-03705180⟩
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