Geochronological and geochemical investigation of the magmatic and sedimentary rocks from the south-eastern tip of the Bayankhongor Zone (central Mongolia) constrains the Neoproterozoic evolution of the northern margin of the Baidrag Block. There, ultramafic to felsic igneous rocks of the Khan-Uul Massif intruded the volcano-sedimentary sequence of the Ulziit Gol Unit. U–Pb zircon ages show that both the plutonic and volcanic rocks were coeval products of the same Ediacaran (598–564 Ma) magmatism. Most of the samples have low contents of high field strength elements typical of arc-related magmas; however, some mafic rock samples display N-MORB-like chemistry. Magmatic rocks in the Khan-Uul Massif and Ulziit Gol Unit yielded exclusively positive initial in zircon values (+4.9 to +13.8), implying derivation from depleted-mantle sources. Furthermore, heterogeneity of the whole-rock initial values (–4.0 to +2.1) documents that fractional crystallization was accompanied by variable crustal contamination. The detrital zircon age patterns of the sandstone and tuffites in the Ulziit Gol Unit indicate that the sequence was filled dominantly by Ediacaran magmatic detritus derived from the Khan-Uul Massif and its volcanic equivalents, while the older cratonic material from the Baidrag basement represented only a subordinate component. Combined magmatic and sedimentary records imply that both the Khan-Uul Massif and the Ulziit Gol Unit may have formed in the same back-arc basin environment. This challenges the previous view that the entire Bayankhongor Zone was ophiolitic in nature. Distribution of coeval Ediacaran supra-subduction systems on the scale of the Mongolian Collage indicates the closure of multiple oceanic basins rimming the Siberian Continent. Following Rodinia break-up, this peri-Siberian realm was presumably formed by sub-parallel continental ribbons and oceanic basins. It is proposed that the amalgamation of these blocks and closure of intervening oceans reflected the Ediacaran advancing mode of the Palaeo-Pacific subduction.